TY - BOOK AU - Kapdi,Anant R. AU - Maiti,Debabrata TI - Strategies for palladium-catalyzed non-directed and directed C-H bond functionalization T2 - Latest trends in Palladium Chemistry SN - 9780128052556 AV - QD411 U1 - 547/.05 23 PY - 2017/// CY - [Place of publication not identified] PB - Elsevier KW - Organometallic chemistry KW - Chemical bonds KW - Catalysis KW - Activation (Chemistry) KW - Carbon KW - Hydrogen KW - SCIENCE KW - Chemistry KW - Organic KW - bisacsh KW - fast KW - Electronic book KW - Electronic books N1 - Includes bibliographical references and index; Front Cover; Strategies for Palladium-Catalyzed Non-Directed and Directed C-H Bond Functionalization; Copyright Page; Contents; List of Contributors; Foreword; 1 Introduction; 2 Directed C-H Bond Functionalization Strategies for Synthesis; 2.1 Introduction; 2.2 Ortho-Palladated C-H Bond Functionalization via Directing Group Effect; 2.2.1 Effect of Coordination Capacity on Functionalization; 2.2.1.1 Heterocycles as Directing Groups for Palladium-Catalyzed C-H Bond Functionalization; 2.2.1.2 Anilides and Ureas as Directing Group for Palladium-Catalyzed C-H Bond Functionalization; 2.2.1.3 Amides as a Directing Group for Palladium-Catalyzed C-H Bond Functionalization2.2.1.4 Carboxylic acids as a Directing Group for Palladium-Catalyzed C-H Bond Functionalization; 2.2.1.5 Carbonyls (Aldehydes and Ketones) as Directing Groups for Palladium-Catalyzed C-H Bond Functionalization; 2.2.1.6 Other Directing Groups for Palladium-Catalyzed C-H Bond Functionalization; 2.3 Conclusion; References; 3 Nondirected C-H Bond Functionalizations of (Hetero)arenes; 3.1 Introduction; 3.2 Reactions With Halides; 3.2.1 Pd-catalyzed C-H/C-X Cross-Coupling Reactions Between an Arene and an Aryl Halide3.2.1.1 Simple Arenes; 3.2.1.2 Polyfluoroarenes; 3.2.2 Pd-catalyzed C-H/C-X Cross-Coupling Reactions Between a Heteroarene and an Aryl Halide; 3.2.2.1 Pyrroles and Indoles; 3.2.2.2 Imidazoles; 3.2.2.3 Pyrazoles and Indazoles; 3.2.2.4 Thiophenes and Benzothiophenes; 3.2.2.5 Furans and Benzofurans; 3.2.2.6 Thiazoles and Benzothiazoles; 3.2.2.7 Oxazoles and Benzoxazoles; 3.2.2.8 Fused Heteroarenes; 3.2.2.9 N-Oxides; 3.2.2.10 Azoles and Other Heteroarenes; Reactions Using Palladium Complexes; Reactions Involving Addition of Phosphine LigandsReactions Under Phosphine-Free Conditions or Without Additional Phosphine Ligands; 3.3 Reactions With Pseudohalides; 3.3.1 Palladium-Catalyzed C-H/C-O Cross-Coupling Reactions With Aryl Sulfonates; 3.3.1.1 Polyfluoroarenes; 3.3.1.2 Heteroarenes; 3.4 Conclusion; References; 4 Palladium-Catalyzed Directed Arylation of Unactivated C(sp3)-H Bonds; 4.1 Introduction; 4.2 Palladium-Catalyzed C(sp3)-H Arylation Directed by Monodentate DGs; 4.3 Palladium-Catalyzed C(sp3)-H Arylation Directed by Bidentate DGs; 4.4 Palladium-Catalyzed C(sp3)-H Arylation Using Transient DGs4.5 Palladium-Catalyzed Asymmetric C(sp3)-H Arylation; 4.5.1 Palladium-Catalyzed Enantioselective C(sp3)-H Arylation With Chiral Ligands; 4.5.2 Palladium-Catalyzed Asymmetric C(sp3)-H Arylation With Chiral Auxiliaries; 4.6 Conclusions and Outlook; References; 5 C-H Bond Functionalization at the Benzene Core of Indoles and Indolines (Excluding C-2 and C-3); 5.1 Palladium-Catalyzed C-H Bond Functionalization of Indole; 5.1.1 C-H Bond Alkenylation of Indole at the C-4 Position UR - http://www.sciencedirect.com/science/book/9780128052549 ER -