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Modern Synthesis Processes and Reactivity of Fluorinated Compounds Progress in Fluorine Science.

Material type: TextTextSeries: Progress in fluorine science seriesPublisher: London : Academic Press, an imprint of Elsevier, [2017]Description: 1 online resourceContent type: text Media type: computer Carrier type: online resourceISBN: 9780128037904; 0128037903Subject(s): Fluorine compounds -- Synthesis | Fluorine compounds -- Reactivity | SCIENCE -- Chemistry -- Inorganic | Fluorine compounds -- SynthesisGenre/Form: Electronic books. | Electronic books.Additional physical formats: Print version:: Modern Synthesis Processes and Reactivity of Fluorinated Compounds.DDC classification: 546.731 LOC classification: QD181.F1Online resources: ScienceDirect
Contents:
Front Cover; Modern Synthesis Processes and Reactivity of Fluorinated Compounds; Progress in Fluorine Science Series; Modern Synthesis Processes and Reactivity of Fluorinated Compounds: Progress in Fluorine Science Series; Copyright; Contents; List of Contributors; Foreword; 1 -- The Cosmic Origin of Fluorine: An Astronomer's View on Fluorine Synthesis; 1. The Cosmic Origin of the Elements; 2. The Cosmic Origin of Fluorine; 2.1 Theoretical Ideas; 2.2 Observations; 2.3 What the Future Holds; References.
2 -- The Fluorine Atom in Health Care and Agrochemical Applications: A Contribution to Life Science1. Introduction; 1.1 The History of Fluorine in Pharmaceutical Applications; 1.2 The History of Fluorine in Agrochemical Applications; 2. Methods to Introduce Fluorine Into Organic Molecules; 2.1 Fluorinating Agents; 2.2 Use of Anhydrous HF; 2.3 Indirect Fluorination: Use of a Building Block Containing a Fluorinated Group; 3. Use of Trifluoromethyl Group in Pharmaceuticals and Agrochemistry; 3.1 Synthesis of Trifluoroacetyl Chloride and Trifluoroacetic Acid.
3.2 Some Active Agrochemical Ingredients Based on Aliphatic Trifluoromethylated Building Blocks3.3 Some Active Pharmaceutical Ingredients Based on Aliphatic Trifluoromethylated Building Blocks; 4. Use of Difluoromethyl Group in Pharmaceuticals and Agrochemistry; 4.1 Synthesis Strategy to Obtain CF2 Groups in Active Ingredients; 4.2 Examples of Active Ingredients Containing the CF2 Group; 4.3 Use of Difluoromethanesulfonyl Chloride; References; 3 -- Industrial Syntheses of Hydrohaloolefins and Related Products; 1. Introduction; 2. Hydrofluoroolefins.
2.1 CHFCF2, 1,1,2-Trifluoroethylene or HFO-11232.2 E, Z-CF3CHHF, 1,3,3,3-Tetrafluoropropene or HFO-1234ze; 2.3 CF3CFCH2, 2,3,3,3-Tetrafluoro-1-propene or HFO-1234yf; 2.3.1 Hexafluoropropene Route; 2.3.2 Tetrafluoroethylene (CF2CF2) Routes; 2.3.3 Tetrafluoroethylene-Chloroform Route; 2.3.4 1230xa (CCl2CClCH2Cl) Route; 2.3.5 240db (CCl3CClHCH2Cl) Route; 2.3.6 1243zf (CF3CHCH2) Route; 2.3.7 114a (CF2ClCF2Cl) and Formaldehyde Route; 2.3.8 Thermal Pyrolysis Processes; 2.4 CF3CFCHF, 1,2,3,3,3-Pentafluoro-1-propene or HFO-1225ye; 2.4.1 Hexafluoropropene Route; 2.4.2 Tetrafluoroethylene Routes.
2.4.3 Tetrafluoroethylene-CFC-12 (CCl2F2) Route2.5 CF3CHCH2, 3,3,3-Trifluoropropene or HFO-1243zf; 2.6 Z-CF3CHCHCF3, 1,1,1,4,4,4-Hexafluoro-2-butene, Z-1336mzz; 2.7 E-CF3CHCHCF3, (E)-1,1,1,4,4,4-Hexafluorobut-2-ene, E-1336mzz; 3. Other Hydrofluoroolefins; 4. Hydrochlorofluoroolefins; 4.1 E-CF3CHCHCl, E-3,3,3-Trifluoro-1-chloropropene, E-1233zd; 4.2 Z-CF3CHCHCl, E-3,3,3-Trifluoro-1-chloropropene, E-1233zd; 4.3 CF3CClCH2, 3,3,3-Trifluoro-2-chloro-1-propene, HFCO-1233xf; 4.3.1 1230xa (CCl2CClCH2Cl) Route; 4.3.2 2,3,3,3-Tetrachloropropene (CCl3CClCH2) 1230xf Route.
Summary: Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds.
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Front Cover; Modern Synthesis Processes and Reactivity of Fluorinated Compounds; Progress in Fluorine Science Series; Modern Synthesis Processes and Reactivity of Fluorinated Compounds: Progress in Fluorine Science Series; Copyright; Contents; List of Contributors; Foreword; 1 -- The Cosmic Origin of Fluorine: An Astronomer's View on Fluorine Synthesis; 1. The Cosmic Origin of the Elements; 2. The Cosmic Origin of Fluorine; 2.1 Theoretical Ideas; 2.2 Observations; 2.3 What the Future Holds; References.

2 -- The Fluorine Atom in Health Care and Agrochemical Applications: A Contribution to Life Science1. Introduction; 1.1 The History of Fluorine in Pharmaceutical Applications; 1.2 The History of Fluorine in Agrochemical Applications; 2. Methods to Introduce Fluorine Into Organic Molecules; 2.1 Fluorinating Agents; 2.2 Use of Anhydrous HF; 2.3 Indirect Fluorination: Use of a Building Block Containing a Fluorinated Group; 3. Use of Trifluoromethyl Group in Pharmaceuticals and Agrochemistry; 3.1 Synthesis of Trifluoroacetyl Chloride and Trifluoroacetic Acid.

3.2 Some Active Agrochemical Ingredients Based on Aliphatic Trifluoromethylated Building Blocks3.3 Some Active Pharmaceutical Ingredients Based on Aliphatic Trifluoromethylated Building Blocks; 4. Use of Difluoromethyl Group in Pharmaceuticals and Agrochemistry; 4.1 Synthesis Strategy to Obtain CF2 Groups in Active Ingredients; 4.2 Examples of Active Ingredients Containing the CF2 Group; 4.3 Use of Difluoromethanesulfonyl Chloride; References; 3 -- Industrial Syntheses of Hydrohaloolefins and Related Products; 1. Introduction; 2. Hydrofluoroolefins.

2.1 CHFCF2, 1,1,2-Trifluoroethylene or HFO-11232.2 E, Z-CF3CHHF, 1,3,3,3-Tetrafluoropropene or HFO-1234ze; 2.3 CF3CFCH2, 2,3,3,3-Tetrafluoro-1-propene or HFO-1234yf; 2.3.1 Hexafluoropropene Route; 2.3.2 Tetrafluoroethylene (CF2CF2) Routes; 2.3.3 Tetrafluoroethylene-Chloroform Route; 2.3.4 1230xa (CCl2CClCH2Cl) Route; 2.3.5 240db (CCl3CClHCH2Cl) Route; 2.3.6 1243zf (CF3CHCH2) Route; 2.3.7 114a (CF2ClCF2Cl) and Formaldehyde Route; 2.3.8 Thermal Pyrolysis Processes; 2.4 CF3CFCHF, 1,2,3,3,3-Pentafluoro-1-propene or HFO-1225ye; 2.4.1 Hexafluoropropene Route; 2.4.2 Tetrafluoroethylene Routes.

2.4.3 Tetrafluoroethylene-CFC-12 (CCl2F2) Route2.5 CF3CHCH2, 3,3,3-Trifluoropropene or HFO-1243zf; 2.6 Z-CF3CHCHCF3, 1,1,1,4,4,4-Hexafluoro-2-butene, Z-1336mzz; 2.7 E-CF3CHCHCF3, (E)-1,1,1,4,4,4-Hexafluorobut-2-ene, E-1336mzz; 3. Other Hydrofluoroolefins; 4. Hydrochlorofluoroolefins; 4.1 E-CF3CHCHCl, E-3,3,3-Trifluoro-1-chloropropene, E-1233zd; 4.2 Z-CF3CHCHCl, E-3,3,3-Trifluoro-1-chloropropene, E-1233zd; 4.3 CF3CClCH2, 3,3,3-Trifluoro-2-chloro-1-propene, HFCO-1233xf; 4.3.1 1230xa (CCl2CClCH2Cl) Route; 4.3.2 2,3,3,3-Tetrachloropropene (CCl3CClCH2) 1230xf Route.

Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds.

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